MATERIALS SCIENCE AND ENGINEERING

DMSE Faculty

> Mark R. DeGuire

Associate Professor (Joined 1987)

• B.S. University of Illinois (Urbana-Champaign) 1980
• M.S. University of Illinois (Urbana-Champaign) 1982
• Ph.D. Massachusetts Institute of Technology 1987

Office: 506 White Phone: 216-368 4221 Email: mrd2@case.edu

Research Group

Research Interests:

• Ceramics and glasses for electronic, chemical, and biomedical applications,
• including thin films, gas sensors, ferrites, fuel cell materials, and apatite coatings on titanium implants;
• synthesis, processing, defect chemistry, microstructure, and phase equilibria.

Teaching Interests

Recent Publications:

• Lijun Zou, Mark De Guire, and Russell Wang,
  "Effect of Organic Self-Assembled Monolayers on the Deposition and Adhesion of Hydroxyapatite Coatings on Titanium,"
  submitted to Z. Metallkd.
• Jing-Jong Shyue and Mark R. De Guire,
  "Deposition of Titanium-Vanadium Oxide Thin Films on Organic Self-Assembled Monolayers: Role of Complexing Agents,"
  Chem. Mater. 17 [22] 5550-5557 (2005).
• Jing-Jong Shyue and Mark R. De Guire,
  "Single-Step Preparation of Mesoporous, Anatase-based Titanium-Vanadium Oxide and Its Application,"
  J. Am. Chem. Soc. 127 [36] 12736-12742 (2005).
• Hillel Pizem, Olga Gershevitz, Yossi Goffer, Aryeh A. Frimer, Chaim N. Sukenik, Uma Sampathkumaran, Xavier Milhet, Alan McIlwain, Mark R. De Guire, Mary Ann B. Meador, and James K. Sutter,
  "Titania Deposition on PMR-15,"
  Chem. Mater. 17 3205-13 (2005).
• Jing-Jong Shyue and Mark R. De Guire,
  "Deposition of Vanadium (V) Oxide Thin Films on Nitrogen-Containing Self-Assembled Monolayers,"
  Chem. Mater. 17 [4] 787-94 (2005).
• Jing-Jong Shyue, Yin Tang, and Mark R. De Guire,
  "Forces between Nitrogen-Containing Self-Assembled Monolayers (SAMs) and Zirconia Particles in Aqueous Solutions,"
  J. Mater. Chem. 15 323-30 (2005).
• Jing-Jong Shyue, Mark R. De Guire, Tsuyoshi Nakanishi, Yoshitake Masuda, Kunihito Koumoto, and Chaim N. Sukenik,
  "Acid-Base Properties and Zeta Potentials of Self-Assembled Monolayers Obtained via in Situ Transformations,"
  Langmuir 20 8693-8698 (2004).
• Yin Tang and Mark R. De Guire,
  "Forces between Sulfonate Self-Assembled Monolayers (SAMs) and Zirconia Particles in Aqueous Solutions,"
  J. Mater. Chem. 14 [7] 1173-9 (2004).
• Y. Masuda, N. Saito, R. Hoffmann, M. R. De Guire, and K. Koumoto,
  "Nano/Micro-Patterning of Anatase TiO2 Thin Film from an Aqueous Solution by Site-Selective Elimination Method,"
  Sci. Technol. Adv. Mater. 4 461-7 (2003).
• Sitthisuntorn Supothina, Mark R. De Guire, and Arthur H. Heuer,
  "Nanocrystalline SnO2 Thin Films via Liquid Flow Deposition,"
  J. Am. Ceram. Soc. 86 [12] 2074-81 (2003).

Proceedings Volumes:

• Organic/Inorganic Hybrid Materials II (Proceedings of Symposium DD, MRS
  Spring Meeting, San Francisco, California, 4-9 April 1999; MRS Symposium
  Proceedings Volume 576), Lisa C. Klein, Lorraine Francis, Mark R. De Guire,
  and James E. Mark, eds. Materials Research Society, Warrendale, PA, 1999.
• Ceramic Nanomaterials and Nanotechnology (Proceedings of Symposium C2,
  "Nanostructured Materials and Nanotechnology," 104th Annual Meeting of the
  American Ceramic Society, 28 April - 1 May, 2002; Ceramic Transactions
  Volume 137), Michael Z. Hu and Mark R. De Guire, eds. American Ceramic
  Society, Westerville, OH, 2003.
• Ceramic Nanomaterials and Nanotechnology II (Proceedings of Symposium 7,
  "Nanostructured Materials and Nanotechnology," 105th Annual Meeting of the
  American Ceramic Society, 27-30 April, 2003; Ceramic Transactions Volume
  148), Mark R. De Guire, Michael Z. Hu, Yury Gogotsi, and Songwei Lu, eds.
  American Ceramic Society, Westerville, OH, 2003 (in press).

Encyclopedia Section:

• M. R. De Guire, with R. W. Cahn and P. D. Calvert,
  "Mineralization on SAMs as a Route to Inorganic Films,"
  Section 2.5, Natural Products and Biomimetics, Article 38.
  In Encyclopedia of Materials: Science and Technology.
  K. H. J. Buschow, R. W. Cahn, M. C. Flemings, B. Ilschner, E. J. Kramer, and S. Mahajan, eds.
  Elsevier Science Ltd., Oxford, England, 2001.

Patents:

• Mark R. De Guire and Warren B. Philipp,
  "Method for Producing Coprecipitated Multicomponent Oxide Powder Precursors,"
  U.S. Patent No. 5,252,314, issued 12 October 1993.
• Mark R. De Guire, Chaim N. Sukenik, and Arthur H. Heuer,
  "Synthesis of Metal Oxide Thin Films,"
  U.S. Patent No. 5,352,485, issued 4 October 1994.
• M. R. De Guire and W. B. Philipp,
  "Method for Producing Coprecipitated Multicomponent Oxide Powder Precursors,"
  U.S. Patent No. 5,298,654, issued 29 March 1994. (Continuation in part of U.S. Patent No. 5,252,314.)
• M. R. De Guire, C. N. Sukenik, and A. H. Heuer,
  "Synthesis of Metal Oxide Thin Films,"
  U.S. Patent No. 5,545,432, issued 13 August 1996 (Continuation in part of U.S. Patent No. 5,352,485.)
• M. Tabib-Azar, J. C. Glass, M. R. De Guire, and K. A. Golonka,
  "Surge Arrestor."
  U. S. Patent No. 5,781,393, issued 14 July 1998.