MATERIALS SCIENCE AND ENGINEERING

Professor De Guire's Research Group

Publications (since 1995) - Journals

1. Jing-Jong Shyue and Mark R. De Guire , "Mesoporous Titanium-Vanadium Oxide " Adv. Func. Mat. (submitted).
2. Jing-Jong Shyue and Mark R. De Guire, "Deposition of Vanadium (V) Oxide Thin Films on Nitrogen-Containing Self-Assembled Monoalyers," Chem. Mater (submitted).
   
3. Jing-Jong Shyue, Yin Tang, and Mark R. De Guire, "Forces between Nitrogen-Containing Self-Assembled Monolayers (SAMs) and Zirconia Particles in Aqueous Solutions", J. Mater. Chem. (accepted).
   
4. Jing-Jong Shyue, Mark R. De Guire, Tsuyoshi Nakanishi, Yoshitake Masuda, Kunihito Koumoto, and Chaim N. Sukenik, "Acid-Base Properties and Zeta Potentials of Self-Assembled Monolayers Obtained via In-Situ Transformations", Langmuir 20 8693-8698 (2004).
   
5. Yin Tang and Mark R. De Guire, "Forces between Sulfonate Self-Assembled Monolayers (SAMs) and Zirconia Particles in Aqueous Solutions", J. Mater. Chem. 14 1173 (2004).
   
6. Y. Masuda, N. Saito, R. Hoffmann, M. R. De Guire, and K. Koumoto, "Site-Selective Deposition and Nano/Micro-Patterning of Anatase TiO2 Thin Film from an Aqueous Solution by Site-Selective Elimination Method", Sci. Technol. Adv. Mater. 4 461 (2003).
   
7. Sitthisuntorn Supothina, Mark R. De Guire, and Arthur H. Heuer, "Nanocrystalline SnO2 Thin Films via Liquid Flow Deposition," J. Am. Ceram. Soc. 86 [12] 2074-2081 (2003) .
   
8. Jing-Jong Shyue, and Mark R. De Guire, "Designing Substrates for Bioinspired Processing of Vanadium Oxide Hydrate (V2O5.nH2O) Thin Films", Advances in Science and Technology, 31 469 (2003).
   
9. Hillel Pizem, Chaim N. Sukenik, Uma Sampathkumaran, Alan K. McIlwain, and Mark R. De Guire, "The Effects of Substrate Surface Composition and Structure on Solution-Deposited TiO2 Thin Films," Chemistry of Materials 14 2476-2485 (2002). [PDF_local]
   
10. U. Sampathkumaran, M. R. De Guire, and R. R. Wang, "Hydroxyapatite Coatings on Titanium," (invited review article), Advanced Engineering Materials 3 [6] 401-5 (2001). [Abstract]
    
11. Thomas P. Niesen and Mark R. De Guire, "Review: Deposition of Ceramic Thin Films at Low Temperatures from Aqueous Solutions" (invited review article), J. Electroceramics 6 [3] 169-207 (2001). [Abstract] [PDF]
    
12. Sitthisuntorn Supothina and Mark R. De Guire, "Characterization of SnO2 Thin Films Grown from Aqueous Solutions," Thin Solid Films 371 [1-2] 1-9 (2000). [PDF_local]
    
13. A. Fischer, F. C. Jentoft, G. Weinberg, R. Schlogl, T. P. Niesen, J. Bill, F. Aldinger, M. R. De Guire, and M. Ruhle, "Characterization of Thin Films Containing Zirconium, Oxygen, and Sulfur by Scanning Electron and Atomic Force Microscopy," J. Mater. Res. 14 [9] 3725-33 (1999). [PDF_local]
    
14. T. P. Niesen, M. R. De Guire, A. Fischer, F. Jentoft, J. Bill, R. Schlogl, F. Aldinger, and M. Ruhle, "Atomic Force Microscopic Studies of Oxide Thin Films on Organic Self-Assembled Monolayers," J. Mater. Res. 14 [6] 2464-74 (1999). [PDF_local]
    
15. Hyunjung Shin, Yuhu Wang, Uma Sampathkumaran, Mark De Guire, Arthur Heuer, and Chaim N. Sukenik, "Pyrolysis of Self-Assembled Organic Monolayers on Oxide Substrates," J. Mater. Res. 14 [5] 2116-23 (1999). [PDF_local]
    
16. Mark R. De Guire, Thomas P. Niesen, Sitthisuntorn Supothina, Jurand Wolff, Joachim Bill, Chaim N. Sukenik, Fritz Aldinger, Arthur H. Heuer and Manfred Ruhle, "Synthesis of Oxide and Non-oxide Inorganic Materials at Organic Surfaces," Z. Metallkd. 89 [11] 758-766 (1998).
    
17. Yuhu Wang, Sitthisuntorn Supothina, Mark R. De Guire, Arthur H. Heuer, Rochael J. Collins, and Chaim N. Sukenik, "Deposition of Compact Hydrous Aluminum Sulfate Thin Films on TiO2 Particles Coated with Organic Self-Assembled Monolayers," Chem. Mater. 10 [8] 2135-44 (1998). [PDF_local]
    
18. Markus Weinmann, Rainer Haug, Joachim Bill, Mark De Guire, and Fritz Aldinger, "Boron-Modified Polysilylcarbodi-imides as Precursors for Si-B-C-N Ceramics: Synthesis, Plastic-Forming and High-Temperature Behavior," Appl. Organometal. Chem. 12 725-34 (1998). [PDF_local]
    
19. Hyunjung Shin, Mark R. De Guire, and Arthur H. Heuer, "Electrical Properties of TiO2 Thin Films Formed on Self-Assembled Organic Monolayers on Silicon," J. Appl. Phys. 83 [6] 3311-7 (1998). [PDF_local]
    
20. Hyunjung Shin, Monika Agarwal, Mark R. De Guire, and Arthur H. Heuer, "Deposition Mechanism of Oxide Thin Films on Self-Assembled Organic Monolayers," Acta Mater. 46 [3] 801-15 (1998). [PDF_local]
    
21. Monika Agarwal, Mark R. De Guire, and Arthur H. Heuer, "Synthesis of Yttrium Oxide Thin Films With and Without the Use of Organic Self-Assembled Monolayers," Appl. Phys. Lett. 71 [7] 891-3 (1997). [PDF_local]
    
22. Monika Agarwal, Mark R. De Guire, and Arthur H. Heuer, "Synthesis of ZrO2 and Y2O3-doped ZrO2 Thin Films Using Self-Assembled Monolayers" J. Am. Ceram. Soc. 80 [12] 2967-81 (1997). [Abstract] [PDF] [PDF_local]
    
23. Hyunjung Shin, Monika Agarwal, Mark R. De Guire, and Arthur H. Heuer, "Solid State Diffusive Amorphization in TiO2/ZrO2 Bilayers," J. Am. Ceram. Soc. 79 [7] 1975-8 (1996).
    
24. Rochael J. Collins, Hyunjung Shin, Mark R. De Guire, Arthur H. Heuer, and Chaim N. Sukenik, "Low Temperature Deposition of Patterned TiO2 Thin Films Using Photopatterned Self-Assembled Monolayers," Appl. Phys. Lett. 69 [6] 860-2 (1996). [PDF_local]
    
25. H. Shin, R. J. Collins, M. R. De Guire, A. H. Heuer, and C. N. Sukenik, "Synthesis and Characterization of TiO2 Thin Films on Organic Self-Assembled Monolayers: II. Film Formation via an Organometallic Route," J. Mater. Res. 10 [3] 699-703 (1995).
    
26. H. Shin, R. J. Collins, M. R. De Guire, A. H. Heuer, and C. N. Sukenik, "Synthesis and Characterization of TiO2 Thin Films on Organic Self-Assembled Monolayers: I. Film Formation from Aqueous Solutions," J. Mater. Res. 10 [3] 692-8 (1995).
    

Publications (since 1995) - Conference Proceedings

1. Yin Tang,* Rocky Mansfield, Nicholas J. Smilanich, and Mark R. De Guire, "Grain Growth of Nanocrystalline SnO 2 in Sol-Gel Derived Thin Films," (proceedings of the symposium on “Nanostructured Materials and Nanotechnology,” 106 th Annual Meeting of the American Ceramic Society, Indianapolis, Indiana, 20 April 2004) (accepted for publication).
   
2. Jing-Jong Shyue and Mark R. De Guire, "Deposition of Titanium-Vanadium Oxide Films on Organic Self-Assembled Monolayers", Proceedings of IUMRS-ICAM 2003, 8th IUMRS International Conference on Advanced Materials, Symposium C2 - Soft Solution Processing, Yokohama, Japan, October 8-13, 2003 (in press).
   
3. Rudolf C. Hoffmann, Shijun Jia, Joachim Bill, Mark R. De Guire and Fritz Aldinger, "Influences of Additives on the Formation of ZnO Thin Films by Forced Hydrolysis,"J. Ceram. Soc. Japan 112 [5] (Supplement 112-1, PacRim5 Special Issue) pp. S1089-S1092 (2004).
   
4. Jing-Jong Shyue and Mark R. De Guire, "Designing Substrates for Bioinspired Processing of Vanadium Oxide Hydrate (V2O5nH2O) Thin Films," Proceedings of CIMTEC 2002 (10th International Ceramics Congress and 3rd Forum on New Materials), Florence, Italy, July 14-18, 2002, P. Vincenzini, ed. Advances in Science and Technology 31 pp. 469-480 (2003).
   
5. Yin Tang, Yao Liu, Uma Sampathkumaran, and Mark R. De Guire,"Recent Results in the Deposition of Ceramic Thin Films at Low Temperatures from Aqueous Solutions," Proceedings of Soft Solution Processing 2000: Novel Fabrication Processing for Inorganic Materials to Sustainable Development in a New Millennium, Tokyo Institute of Technology, O-okayama, Meguro, Tokyo, Japan, 11 December 2000, Solid State Ionics 151 [1-4] pp. 69-78 (2002).
   
6. Thomas P. Niesen and Mark R. De Guire, "Review: Deposition of Ceramic Thin Films at Low Temperatures from Aqueous Solutions," Proceedings of Soft Solution Processing 2000: Novel Fabrication Processing for Inorganic Materials to Sustainable Development in a New Millennium, Tokyo Institute of Technology, O-okayama, Meguro, Tokyo, Japan, 11 December 2000, Solid State Ionics 151 [1-4] pp. 61-68 (2002).
   
7. T. P. Niesen, U. Sampathkumaran, T. Fuchs, M. R. De Guire, J. Bill, and F. Aldinger, "Deposition of Nanocrystalline Zirconia Thin Films on Organic Self-Assembled Monolayers by a Continous Flow Technique," "MATERIALS WEEK 2000 - Proceedings," editor and organiser: Werkstoffwoche-Partnerschaft, Frankfurt, 25-28 September 2000, URL: www.materialsweek.org/proceedings.
   
8. U. Sampathkumaran, S. Supothina, R. Wang, and M. R. De Guire, "Ceramic Thin Films on Organic Self-Assembled Monolayers: Synthesis and the Mechanism of Formation," pp. 177-88 in Mineralization in Natural and Synthetic Biominerals (Proceedings of Symposium DD, MRS Fall Meeting, Boston, Massachusetts, 29 November - 3 December 1999; MRS Symposium Proceedings 599), P. Li, P. Calvert, R. J. Levy, T. Kokubo, C. R. Scheid, eds. Materials Research Society, Warrendale, PA, 2000.
   
9. S. Supothina, M. R. De Guire, A. H. Heuer, T. P. Niesen, J. Bill, and F. Aldinger, "Deposition of Nanocrystalline Tin (IV) Oxide Films On Organic Self-Assembled Monolayers," pp. 203-8 in Organic/Inorganic Hybrid Materials II (Proceedings of Symposium DD, MRS Spring Meeting, San Francisco, California, 4-9 April 1999; MRS Symposium Proceedings Volume 576), Lisa C. Klein, Lorraine Francis, Mark R. De Guire, and James E. Mark, eds. Materials Research Society, Warrendale, PA, 1999.
   
10. T. P. Niesen, J. Wolff, J. Bill, M. R. De Guire, and F. Aldinger, "Synthesis and Characterization of Titania and Vanadia Thin Films at Organic Self-Assembled Monolayers," pp. 197-202 in Organic/Inorganic Hybrid Materials II (Proceedings of the symposium on Organic-Inorganic Hybrid Materials, MRS Spring Meeting, San Francisco, California, 4-9 April 1999; MRS Symposium Proceedings Volume 576), Lisa C. Klein, Lorraine Francis, Mark R. De Guire, and James E. Mark, eds. Materials Research Society, Warrendale, PA, 1999.
    
11. Hyunjung Shin, Yuhu Wang, Sitthisuntorn Supothina, Rochael J. Collins, Monika Agarwal, Mark R. DeGuire, Arthur H. Heuer, and Chaim N. Sukenik, "Siloxane-Anchored Monolayers as Templates for Oxide Film Deposition," pp. 1-13 in Fundamental and Applied Aspects of Chemically Modified Surfaces (Proceedings of The 7th International Symposium on Chemically Modified Surfaces, Chicago, Illinois, June 1998), J. Blitz and C. B. Little, eds. Royal Society of Chemistry, 1999.
    
12. U. Sampathkumaran, M. R. De Guire, A. H. Heuer, T. Niesen, J. Bill, and F. Aldinger, "Formation of Self-Assembled Monolayers and Ceramic Films on Semiconductor and Oxide Substrates," pp. 307-18 in Innovative Processing and Synthesis of Ceramics, Glasses, and Composites II (Proceedings of the symposium, Cincinnati, Ohio, 4-6 May, 1998), Narottam P. Bansal and J. P. Singh, eds. Ceramic Transactions 94, American Ceramic Society, Westerville, Ohio, 1999.
    
13. Mark R. De Guire, Thomas P. Niesen, Jurand Wolff, Sitthisuntorn Supothina, Joachim Bill, Fritz Aldinger, and Manfred Ruhle, "Synthesis of Oxide and Non-oxide Inorganic Materials at Organic Surfaces," pp. 143-61 in Precursor-Derived Ceramics - Synthesis, Structure and High-Temperature Mechanical Properties, (Proceedings of the workshop on Grain Boundary Dynamics of Precursor-Derived Covalent Ceramics, Schloss Ringberg, Germany, 10-14 November, 1996), J. Bill, F. Wakai, and F. Aldinger, eds. Wiley-VCH Verlagsgesellschaft mbH, Weinheim, 1999.
    
14. Mark R. De Guire, Hyunjung Shin, Rochael Collins, Monika Agarwal, Chaim N. Sukenik, and Arthur H. Heuer, "Deposition of Oxide Thin Films on Silicon Using Organic Self-Assembled Monolayers," in Integrated Optics and Microstructures III, Massood Tabib-Azar, ed. Proc. SPIE 2686, pp. 88-99 (1996).
    
15. Paul W. Angel, Mark R. De Guire, and Alfred R. Cooper, "Electrical Conductivity, Relaxation, and the Glass Transition: A New Look at a Familiar Phenomenon," in Optical and Electrical Properties of Glasses: Proceedings of the 13th University Conference on Glass Science (Troy, New York, 9-11 August 1995), M. Tomozawa, C. T. Moynihan, and S. N. Crichton, eds. J. Non-Cryst. Solids 203 286-92 (1996).

Proceedings Volume

1. Ceramic Nanomaterials and Nanotechnology II (Proceedings of Symposium 7, “Nanostructured Materials and Nanotechnology,” 105th Annual Meeting of the American Ceramic Society, 27-30 April, 2003; Ceramic Transactions Volume 148 ), Mark R. De Guire, Michael Z. Hu, Yury Gogotsi, and Songwei Lu, eds. American Ceramic Society, Westerville, OH, 2003.
   
2. Ceramic Nanomaterials and Nanotechnology (Proceedings of Symposium C2, "Nanostructured Materials and Nanotechnology," 104th Annual Meeting of the American Ceramic Society, 28 April - 1 May, 2002; Ceramic Transactions Volume 137), Michael Z. Hu and Mark R. De Guire, eds. American Ceramic Society, Westerville, OH, 2002 (in press).
   
3. Organic/Inorganic Hybrid Materials II (Proceedings of Symposium DD, MRS Spring Meeting, San Francisco, California, 4-9 April 1999; MRS Symposium Proceedings Volume 576), Lisa C. Klein, Lorraine Francis, Mark R. De Guire, and James E. Mark, eds. Materials Research Society, Warrendale, PA, 1999.

Encyclopedia Section

1. Mark R. De Guire, "Mineralization on SAMs as a Route to Inorganic Films," Section 2.5, Natural Products and Biomimetics, Article 38. In Encyclopedia of Materials: Science and Technology. K. H. J. Buschow, R. W. Cahn, M. C. Flemings, B. Ilschner, E. J. Kramer, and S. Mahajan, eds. Elsevier Science Ltd., Oxford, England, 2001.
   

Patents

1. Massood Tabib-Azar, John C. Glass, Mark R. De Guire, and Kenneth A. Golonka, "Surge Arrestor." U. S. Patent No. 5,781,393, issued 14 July 1998.
   
2. Mark R. De Guire, Chaim N. Sukenik, and Arthur H. Heuer, "Synthesis of Metal Oxide Thin Films," U.S. Patent No. 5,545,432, issued 13 August 1996 (Continuation in part of U.S. Patent No. 5,352,485.)

Invited Presentations

1. "Forces between Organic Self-Assembled Monolayers and Oxides, and Their Effects on Oxide Film Deposition," The Weizmann Institute, Department of Materials and Interfaces, Rehovot , Israel , 8 January 2004.
   
2. "Engineered Ceramic-Organic Interfaces: Designing Surfaces For Deposition Of Ceramic Thin Films," The Technion, Department of Materials Engineering, Haifa , Israel , 4 January 2004.
   
3. "Forces between Organic Self-Assembled Monolayers and Oxides, and Their Effects on Oxide Film Deposition," Bar Ilan University, Department of Chemistry, Ramat Gan , Israel , 31 December 2003.
   
4. "Engineered Ceramic-Organic Interfaces," Composites at Lake Louise — The Role of Interfaces within and between Composites, Lake Louise , Canada , 19-24 October 2003.
   
5. "Particle-Surface Interactions Mediated by Organic Self-Assembled Monolayers," Particles 2003 Conference on Imaging, Marking and Printing Applications of Particle Technology, Toronto, Canada, 23-26 August 2003.
   
6. "Nanoscale Measurements of Forces between Ceramics and Model Surfaces," in the Symposium on Structure at the Limit of Resolution: A Symposium to Celebrate Manfred Ruehle's 65th Birthday at the 105th Annual Meeting & Exposition of the American Ceramic Society, Nashville, Tennessee, 27-30 April 2003.
   
7. "Functionalized Organic Substrates for Titania and Vanadia Thin Films," Workshop on "Bioinspired Approaches for Advanced Materials," Schloss Ringberg, Tegernsee, Germany, 13 March 2002.
   
8. "Designing Substrates for Bioinspired Processing of Ceramic Thin Films," CIMTEC 2002 (10th International Ceramics Congress and 3rd Forum on New Materials), Florence, Italy, July 14-18, 2002.
   
9. "Deposition of Compact Hydrous Aluminum Sulfate Thin Films on TiO2 Particles Coated with Organic Self-Assembled Monolayers," Meeting of the Technical Committee of IFPRI (International Fine Particle Research
   Institute), CWRU, April 8, 2002.
   
10. "Ceramic Thin Films on Functionalized Surfaces: the Role of the Substrate," Workshop on "Biomimetic Materials Processing," Schloss Ringberg, Tegernsee, Germany, 9 October 2001.
    
11. "Review: Deposition of Ceramic Thin Films at Low Temperatures from Aqueous Solutions," International Symposium on Soft Solution-Processing: Novel Fabrication Processing for Inorganic Materials to Sustainable Development in a New Millennium, Tokyo Institute of Technology, O-okayama, Meguro, Tokyo, Japan, 11 December 2000.
    
12. "Ceramic Oxide Thin Films on Organic Self-Assembled Monolayers: Synthesis and the Mechanism of Formation," keynote address at the 4th International Workshop on Design and Soft Solution Processing for Advanced Inorganic Materials, Tokyo Institute of Technology, Yokohama, Japan, 28 February 2000.
    
13. "Ceramic Thin Films on Organic Self-Assembled Monolayers: Synthesis and the Mechanism of Formation," Symposium on "Mineralization in Natural and Synthetic Biomaterials," Fall Meeting of the Materials Research Society, Boston, Massachusetts, 30 November 1999.
    
14. "Deposition of Nanocrystalline Tin (IV) Oxide Films on Organic Self-Assembled Monolayers," Max-Planck-Institut fur Metallforschung, Pulvermetallurgisches Laboratorium, Stuttgart, Germany, 1 July 1999.
    
15. "Deposition of Ceramic Thin Films from Aqueous Solutions at Low Temperatures," Max-Planck-Institut fur Metallforschung, Pulvermetallurgisches Laboratorium, Stuttgart, Germany, 20 October 1998.
    
16. "Deposition of Ceramic Thin Films from Aqueous Solutions at Low Temperatures - the Roles of the Source and the Substrate," Gordon Research Conference on Solid State Studies in Ceramics, Kimball Union Academy, 4 August 1998.
    
17. "Ceramic Thin Films on Organic Self-Assembled Monolayers: Examples and Capabilities," Minnesota Section of the American Ceramic Society, Minneapolis, Minnesota, 14 April 1998.
    
18. "Ceramic Thin Films on Organic Self-Assembled Monolayers: Synthesis and the Mechanism of Formation," Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota, 14 April 1998.
    
19. "Ceramic Thin Films on Organic Self-Assembled Monolayers: the Role of the Substrate," Department of Materials, University of California at Santa Barbara, 7 April 1998. (Symposium in honor of Prof. Manfred Ruhle's 60th birthday)
    
20. "Ceramic Thin Films on Organic Self-Assembled Monolayers: Studies of the Deposition Mechanism," Department of Materials Science and Engineering, Case Western Reserve University, 7 October 1997.
    
21. "Ceramic Thin Films on Organic Self-Assembled Monolayers," Technical Center, Caterpillar Inc., Peoria, Illinois, 15 August 1997.
    
22. "The Synthesis of Ceramic Thin Films on Organic Self-Assembled Monolayers," Fritz-Haber-Institut, Berlin, Germany, 14 March 1997.
    
23. Thomas Niesen and Mark De Guire, Status Seminar of the Powder Metallurgy Laboratory of the Max-Planck-Insitut fur Metallforschung, Schloss Ringberg, Tegernsee, Germany, 20 February 1997.
    
24. "Synthesis of Oxide Inorganic Materials at Organic Surfaces," workshop on "Grain Boundary Dynamics of Precursor-Derived Covalent Ceramics," Schloss Ringberg, Tegernsee, Germany, 12 November 1996.
    
25. "Ceramic Thin Films on Organic Self-Assembled Monolayers," Engelhard Corporation, Beachwood, Ohio, 24 April 1996.
    
26. Invited presenter, Workshop on Compound Semiconductor Materials and Devices (WOCSEMMAD), Santa Fe, New Mexico, 19 February 1996.
    
27. "Deposition of Oxide Thin Films on Silicon Using Organic Self-Assembled Monolayers," SPIE '96, San Jose, California, 29 January 1996.
    
28. "Ceramic Thin Films on Organic Self-Assembled Monolayers," Max-Planck-Institut fur Metallforschung, Stuttgart, Germany, 23 October 1995.
    
29. "Ceramic Thin Films on Organic Self-Assembled Monolayers," Argonne National Laboratory, Argonne, Illinois, 3 August 1995.
    
30. "Ceramic Thin Films on Organic Self-Assembled Monolayers," Hanscom Air Force Base, Bedford, Massachusetts, 24 July 1995.